Chemical Engineering Thermodynamics
In an irreversible process
- A. Tds = dE – dW = 0
- B. DE – dW – Tds = 0
- C. Tds – dE + dW< 0
- D. Tds – dT + dW< 0
From second law of thermodynamics :
TdS⩾δQ
⇒TdS⩾dU+δW
For an irreversible process TdS−dU−δW>0
And for an reversible process TdS−dU−δW=0